%0 Journal Article 
%A Cano Sierra, Jesús
%A Sudupe Ormeño, María
%A Royo Gracia, Pascual
%T Synthesis and reactivity of di(silylamido)cyclopentadienyl titanium and zirconium complexes
%D 2007
%@ 0022-328X
%U http://hdl.handle.net/10017/4170
%X We present in this account the synthesis and recent developments of a new class of group 4 metal complexes with the tridentate di(silylamido)cyclopentadienyl ligand. These doubly silyl-bridged group 4 metal amido chelates are receiving increasing interest as they are efficient catalysts for ethene polymerization when activated with MAO despite generating 14-electron d0 cationic species free of the alkyl group required for the first insertion reaction in the polymerization process.
%K Silylamido
%K Cyclopentadienyl
%K Titanium
%K Zirconium
%K Ciencia
%K Química inorgánica
%K Science
%K Chemistry, inorganic
%~ Biblioteca Universidad de Alcala