%0 Journal Article %A Álvarez-Builla Gómez, Julio %A Crespo, Teresa %A López, Raquel %A Elguero, José %A Toiron, Catherine %A Yranzo, Gloria I. %T High-performance liquid-chromatographic determination of the pi-values of azol-N-yl substituents %D 1992 %@ 0022-3549 %U http://hdl.handle.net/10017/3920 %X The π (hydrophobic constant) values for 16 parent azoles (pyrrole, imidazole, pyrazole, four triazoles, two tetrazoles, indole, benzimidazole, 1 H and 2H-indazoles, 1H-and 2H-benzotriazoles, and carbazole) were calculated from the logarithms of the capacity factors (log k′) determined by HPLC. The values thus obtained are discussed according to an additive model in which the number and position of pyridinelike nitrogen atoms and the annelation effect are considered. %K Hydrophobicity measurements %K Partition-coefficients %K Behavior %K Water %K Ciencia %K Química orgánica %K Science %K Chemistry, organic %~ Biblioteca Universidad de Alcala