%0 Journal Article 
%A Martín Alonso, Avelino
%A Martínez Espada, Noelia
%A Mena Montoro, Miguel
%A González Mosquera, Marta Elena
%A Pérez Redondo, Adrián
%A Yélamos Sánchez, Carlos
%T Mercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systems
%D 2008
%@ 1359-7345
%U http://hdl.handle.net/10017/38492
%X The imido - nitrido complex [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl) amide reagents to afford [M-2{(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti-3(eta(5)-C5Me5)(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.
%K Química
%K Chemistry
%~ Biblioteca Universidad de Alcala