%0 Journal Article %A Greño Ocariz, Maider %A Mena Montoro, Miguel %A Pérez Redondo, Adrián %A Yélamos Sánchez, Carlos %T Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes %D 2017 %@ 1477-9226 %U http://hdl.handle.net/10017/38446 %X Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine‒borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with Zr···H-B interactions which readily undergo β-hydride elimination to give hydride functions. %K Química %K Chemistry %~ Biblioteca Universidad de Alcala